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Remove Office 365 federation from ADFS server

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1. Check federation status
PS C:\Users\administrator> Get-MsolDomain | fl name,status,auth*

Name           : mfalab3.com
Status         : Verified
Authentication : Federated

2. From ADFS server, run following Powershell commands

Set-MsolADFSContext -Computer th-adfs2012
Set-MsolDomainAuthentication -Authentication Managed -DomainName mfalab3.com 
Get-MsolDomain | fl name,status,auth* 
(Note : th-adfs2012 : adfs server, mfalab3.com : test domain name)

3. Check federation status again

PS C:\Users\administrator> Get-MsolDomain | fl name,status,auth*

Name           : mfalab3.com
Status         : Verified
Authentication : Managed

4. Login to Office 365 to check if it is not redirected to ADFS server