ASMX 2.0, WSE 3.0 and WCF
Web Services were enhanced with the release of .NET Framework 2.0 and then came along WSE 3.0 in December 2005 and in January 2006 Microsoft announced GO-LIVE licensing for Windows Communication Foundation (formerly known as Indigo). If you are confused about all this then I would highly recommend that you read Aaron Skonnard article in which he answers the most common questions on ASMX, WSE 3.0 and WCF.