Hello Jay Lin,
Thank you for reaching out to Microsoft!
For fetching the list of users in your application via API request in Postman, you can try the following mentioned workarounds as per the error mentioned.
Try granting application permissions to the app in the Entra portal and Grant admin consent, generate a new token and execute the API to get the list of all users using application permissions as per the documentation referenced below.
Link: Get users via Graph API
Else, try executing the Graph API by signing in as a user in the Graph explorer to get the list of users.
Here is the link for troubleshooting the error mentioned.
Link: Troubleshoot Authorization Request denied using Graph API
You can decode the token using jwt.ms/jwt.io to check the roles and permissions.
Hope this helps.
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