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Hi @Sachidhanantham Ramalingam
The policies you configure are almost right. For this policy Configure the Enterprise Mode Site List, you can set the value to file:///D:/site.xml.
After you set the group policies, there's no need to set registry settings again. The registry path you show in pdf is not right. The right registry setting for policy Configure the Enterprise Mode Site List should be like this:
If the issue persists, please open edge://policy/ page and edge://compat/iediagnostic page in Edge browser in machine B and provide the screenshots of the pages. Please also provide your D:/site.xml file for checking.
If you want your app to work in Edge natively, you'll have to change the old code totally to make it compatible with Edge. There's no way to achieve this without making major code changes.
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Regards,
Yu Zhou