Hi Dan, The general availability status for NAA is documented here: https://learn.microsoft.com/en-us/javascript/api/requirement-sets/common/nested-app-auth-requirement-sets. We'll update that as NAA is GA on more platforms.
When NAA is not available, msal-browser will automatically fall back to using a public client application and use a dialog to sign in the user. However on some older Outlook clients there is a bug that causes an "about" error to show to the user. There's a fallback workaround for this in the sample https://github.com/OfficeDev/Office-Add-in-samples/tree/main/Samples/auth/Outlook-Add-in-SSO-NAA
Details are in the readme about fallback.
And for a list of which older platforms used the trident (IE11) webview, see https://learn.microsoft.com/en-us/office/dev/add-ins/concepts/browsers-used-by-office-web-add-ins
Cheers,
David