Sure, but you will have to use leverage some MFA solution. Its not built-in to ADFS:
To use Azure MFA:
Third Party Solutions:
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Hello,
We have our AD/ADFS hosted in azure on a vm ( not Azure AD) and are using it as identity provider for external applications ,now we have a requirement to enable MFA for a particular SaaS application , is it possible to enable MFA without Azure AD?
Sure, but you will have to use leverage some MFA solution. Its not built-in to ADFS:
To use Azure MFA:
Third Party Solutions: