@Namless Shelter, Thanks for posting in Q&A. For root CA certificate, I would like to say yes, you would still need the Root CA cert file for the 802.1x wifi policy for Domain Joined PC or Macs. The Root CA cert establishes trust from the device to the issuing CA from which the other certificates are issued. While Intune supports SCEP and PKCS certificate profiles, the trusted root certificate must still be deployed to the same devices and users that receive the certificate profiles for SCEP and PKCS. Therefore, it is not pointless to set up the Intune Connector for SCEP and PKCS. NPS would still need to authenticate with a Root CA preloaded to only AD existed devices (Windows & Mac) to allow Domain Joined Devices to connect to Wifi.
SCEP and PKCS are both certificate profiles in Intune used to provision certificates on devices for authentication. The main difference between the two is that SCEP provisions unique certificates for each request, while PKCS provisions each device with a unique certificate. SCEP can also be used to provision certificates on user-less devices like kiosks. On the other hand, PKCS can deploy a certificate type of either user or device, with user certificates requiring user affinity.Here are links with mroe details.
https://learn.microsoft.com/en-us/mem/intune/protect/certificates-scep-configure
https://learn.microsoft.com/en-us/mem/intune/protect/certificates-pfx-configure
Hope the above information can help.
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