Hello @Marcos Correa ,
Thank you for reaching out Microsoft Q&A.
I Understand you configured Cisco DUO as an External authentication method for testing but When you attempt to access office.com, you do not receive the prompt to choose the external authentication method(DUO). However if I were to open the web browser in private mode, I do receive the Cisco Duo.
Your regular browser session might be retaining some state or cookies that are causing it to default to Microsoft Authenticator instead of prompting for DUO. Clearing your browser cache and cookies might resolve the issue.
If you're still experiencing the issue after clearing your browser cache and cookies, you should revoke all MFA sessions for the affected user. This is because the previous MFA for the Microsoft authenticator may be cached in the claim, preventing the MFA prompt from appearing. Ensure that all MFA sessions are revoked and then try again.
For additional information and known limitations follow the document: https://duo.com/docs/microsoft-eam#create-the-duo-entra-id-application
If you have any further questions or need additional assistance, please don’t hesitate to reach out.