As this is based in AVS we do not have permissions to rescan storage or refresh the inventory.
I was able to log this with MS support who resolved the issue.
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I have recently deleted an ANF datastore from our AVS environment.
I first removed it from storage on the AVS blade, then removed the volume from Azure NetApp files.
The datastore is still present in the vCentre GUI, however it has been marked as (inaccessible).
As this is based in AVS we do not have permissions to rescan storage or refresh the inventory.
I was able to log this with MS support who resolved the issue.