Hello @Khezar Butt ,
Thank you for Reaching out Microsoft Q&A.
I Understand that you recently migrated from one IdP to another and you are having some trouble with seamless SSO. You have Hybrid environment with Entra connect sync.
You Noticed that users are not receiving the AzurePRT token from Entra ID and are unable to verify their credentials.If you suspect that a PRT problem exists, I recommend that you first collect Microsoft Entra logs, and follow the steps that are outlined in the troubleshooting checklist. For Trouble shooting steps please check with the document: https://learn.microsoft.com/en-us/entra/identity/devices/troubleshoot-primary-refresh-token#troubleshooting-checklist
As you mentioned that you migrated to the another IDP if it is third party identity provider it needs to support the WS-Trust protocol to enable PRT issuance on Windows 10 or newer devices.
Hope this helps. If you have any further questions or need additional assistance, please don’t hesitate to reach out.