@MMK, Thanks for posting in Q&A. From your description, it seems you want the WiFI connects automatically. In your configuration, I find "Connect automatically when in range:", is set no. When Yes, devices connect automatically when they're in range of this network. When No, devices don't automatically connect and it needs to enter username and password. Please change it to yes to let it automatically connects.
https://learn.microsoft.com/en-us/mem/intune/configuration/wi-fi-settings-windows#enterprise-profile
Please try the above suggestion and if there's any update, feel free to let us know.
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