Hello @Yasin Turan ,
Thank you for reaching out Microsoft Q&A.
I understand you are not receiving the emails from Microsoft Azure for the PIM roles activation
If an approval request is approved in the Azure portal before the first email is sent, the first email will no longer be triggered, and other approvers won't be notified by email of the approval request. It might appear as if they didn't get an email but it's the expected behavior.
This can also result from the information provided in the below Screenshot.
for more information: https://learn.microsoft.com/en-us/entra/id-governance/privileged-identity-management/pim-email-notifications?source=recommendations
Hope this helps. Do let us know if you any further queries.
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Regards,
Goutam Pratti.