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Hi @Kevin R
That's by design in Chromium. If none of the three save options meet your demands, you can try to search if there's any save page extension which you can use. Or save the page as PDF using Ctrl+P print options.
Besides, you mention that you used IE before to save pages. Now, you can load the page in Edge IE mode, and enable this policy Enable extended hot keys in Internet Explorer mode. Then you'll be able to save the content of the page loading in IE mode using Ctrl+S. I think it will provide the same experience using IE to save pages.
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Regards,
Yu Zhou