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As per my understanding, you are trying to change the high availability configuration for an Azure PostgreSQL Flexible Server from a same zone setup to a zone-redundant setup.
Yes, you can change the high availability configuration for an Azure PostgreSQL Flexible Server from a same zone setup to a zone-redundant setup. This can be done through the Azure portal or using the Azure portal, Azure CLI, or Azure PowerShell.
Impact: Changing the high availability configuration to a zone-redundant setup may have some impact, such as:
Increased Latency: There might be a slight increase in latency for write operations due to synchronous replication across zones.
Cost: There will be an increase in cost associated with deploying a standby server in a different availability zone.
For detailed steps and more information, you can refer to the below documents:
https://learn.microsoft.com/en-us/azure/postgresql/flexible-server/how-to-configure-high-availability?tabs=portal-enable-existing-server%2Cportal-disable-existing-server%2Cportal-enable-new-server%2Cportal-forced-failover%2Cportal-planned-failover#enable-high-availability-for-existing-servers
https://learn.microsoft.com/en-us/azure/reliability/reliability-postgresql-flexible-server
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