@Vennapusa, Sudharshan R, Thanks for posting in Q&A. Yes, we can create different provisioning policies and assign to different users in different user group.
https://learn.microsoft.com/en-us/windows-365/enterprise/create-provisioning-policy
In the provisioning policy, we can configure different network. For Microsoft Entra Join: You have two options for Network:
Microsoft-Hosted Networks: This option is ideal for simplicity and ease of management. You can use Microsoft Entra join (formerly Azure AD join) to connect your Cloud PCs to a Microsoft-hosted network
Azure Network Connections (ANCs): This allows you to provision Cloud PCs that are attached to a virtual network you manage in Azure. You can create multiple ANCs, each with its own configuration
https://learn.microsoft.com/en-us/windows-365/enterprise/create-azure-network-connection
Hope the above information can help.
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